Research into wetting agents

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For many of us, wetting agents are common tools we use for the purposes of conserving irrigation water and/or managing soil water repellency.

It has been estimated that, on average, the U.S. golf industry uses more than 2 billion gallons of irrigation water on a daily basis, and wetting agents are the No. 1 measure adopted by 92% of golf facilities for water management (18).

On golf courses, especially on sand-based growing medium such as USGA greens, soil water repellency is, unfortunately, an inevitable condition. Although soil water repellency can occur on all soil types, coarser particles, such as the sands used to build and/or topdress greens, are more susceptible to the development of water repellency because they have a significantly smaller (>105 times) specific surface area (area/mass) compared with peat and clay (3). It is also argued that the significantly smaller specific surface area, along with the higher distribution of macropores found in sandy soils, provides a preferred habitat for fungal growth rather than bacteria, further promoting the development of soil water repellency (8). Consequently, water bypasses repellent areas and forms preferential flow, leading to the development of localized dry spot. Regardless of management intensity, water repellency will eventually develop, and localized dry spot may be observed on sand-based greens as soon as six months after construction (19).

Water repellency, or hydrophobicity, is a phenomenon in which a surface repels water into individual droplets, thus inhibiting water infiltration into porous mediums such as soil. This “repelling force” is caused by strong cohesion within the water body, which is termed surface tension or surface-free energy.

Under normal conditions (68 F; 20 C), surface tension of water is 72.75 millinewtons/meter (15). Surfaces with a surface-free energy greater than 72.75 millinewtons/meter possess stronger adhesive forces than the cohesive force within water, which forces attraction with contacting water molecules and spreads them over the surfaces, sequentially retaining water and forming hydrophilic surfaces. When a soil medium becomes hydrophobic because of an accumulation of organic acids, its surface-free energy decreases to below 72.75 millinewtons/meter, resulting in a failed attraction to bypass water molecules and, inevitably, the development of water repellency. Addition of wetting agents — amphiphilic molecules with hydrophobic tails and hydrophilic heads in their chemical structures — reduces the surface tension of water and simultaneously allows the wetting agents to pass into the soil, thereby increasing infiltration and water retention (17).

Since the development of the first patented wetting agent product — a blend of nonionic surfactants such as alkylphenol ethoxylate (6) — and the early research that investigated soil water repellency on turf in the 1960s (13), tremendous advances have been made in various wetting agents that include formulations with ethylene oxide and propylene oxide block copolymers (1, 2, 7), for the purposes of increasing water infiltration, promoting homogeneous soil moisture and, if possible, preventing the development of soil water repellency. Performance of those wetting agents, however, is dramatically influenced by formulations, application rates and environmental conditions (5, 12). This article, therefore, aims to summarize some of our recent research findings regarding inherent differences among wetting agents and, we hope, provide guidance in selecting the appropriate wetting agents to meet various goals.

Effect of wetting agents on surface tension of water

As described above, adding wetting agents can reduce the surface tension of water, allowing the wetting agents to enter the hydrophobic soil medium and thereby facilitate infiltration. In this laboratory-based experiment, 15 commonly used wetting agents in the turf market (see the 15 products in Table 1) were mixed with water at five rates — 4, 2, 1, 0.5 and 0.25 times the rates suggested on the label — before determining their surface tension using the Attention Theta Lite tensiometer (Biolin Scientific). This experiment was designed as a completely randomized design with a factorial combination of wetting agents and various rates, with three replications and two repeats.

A wide range of surface tension was seen among the 15 selected wetting agents (Figure 1, below). The highest surface tension found was 44.8 millinewtons/meter at label rate, produced by InfilTRx. The lowest surface tension was 22.0 millinewtons/meter, which was caused by applying Break-thru S240 at the label rate and was less than half the surface tension from InfilTRx. For reference, the surface tension of tap water in our laboratory was 72.8 millinewtons/meter.

Wetting agents surface tension
Figure 1. Distribution of surface tension (millinewtons/meter) of 15 wetting agents at 4, 2, 1, 0.5 and 0.25 times the label suggested rates.

These results suggested that all wetting agents tested, regardless of rates, substantially reduced the surface tension of water, indicating improved infiltration into a hydrophobic soil surface. We also saw a trend of lower surface tension generally being associated with higher concentrations of the same product. Our early research found a negatively correlated relationship between surface tension and hydraulic conductivity for a given wetting agent solution (17). Therefore, a wetting agent that produces relatively higher surface tension is likely to produce relatively lower infiltration into hydrophobic soil.

Effect of wetting agent on water infiltration

In the laboratory, six wetting agents were then tested for their effect on water infiltration into hydrophobic sands. The wetting agents selected were H2O Maximizer (KALO), TriCure AD (Mitchell Products), Capacity (Becker Underwood), Aqueduct (Aquatrols), Primer Select (Aquatrols) and InfilTRx (Aquatrols).

Sands that meet the USGA recommendation for green construction were treated with octadecylamine in the laboratory to create steady hydrophobicity at 7.2 molar (based on the molarity of ethanol droplet test) (11). This level of hydrophobicity is categorized as severely water-repellent (10). The sand was then packed uniformly in an infiltration system made of PVC pipes, and the infiltration of the selected wetting agents at their label-suggested rates was determined with the method described in our earlier publication (17). This experiment was a completely randomized design, with three replications and one repeat.

Wetting agents infiltration
Figure 2. Infiltration of six selected wetting agents into hydrophobic sand. The water-only treatment did not penetrate into the hydrophobic sand, hence its infiltration was not generated.

All wetting agents were tested at their highest label-suggested rates. Within 30 minutes after application, and by 10 minutes into ponding, all the selected wetting agents reached a steady infiltration rate (Figure 2, above). The steady infiltration rates of Capacity and Aqueduct reached 1.06 inch (27 millimeters)/minute, while the other four products maintained a steady rate of 0.94 to 0.98 inch (24 to 25 millimeters)/minute. All the rates surpassed the minimum saturated hydraulic conductivity of 0.1 inch (2.5 millimeters)/minute recommended by USGA for green construction. Under the testing conditions, tap water alone was not able to penetrate into this severely hydrophobic sand, hence no infiltration data were presented.

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